The Parent Borylene: Betwixt and Between
Identifieur interne : 007922 ( Main/Exploration ); précédent : 007921; suivant : 007923The Parent Borylene: Betwixt and Between
Auteurs : Dennis P. Curran [États-Unis] ; Anne Boussonnière [États-Unis] ; Steven J. Geib [États-Unis] ; Emmanuel Lacôte [France]Source :
- Angewandte Chemie International Edition [ 1433-7851 ] ; 2012-02-13.
English descriptors
- KwdEn :
- Aliphatic, Aliphatic products, Alkyl, Alkyl halides, Angew, Angewandte, Anion, Boriranes, Boryl, Boryl dichlorides, Borylene, Braunschweig, Chem, Cleaner crude product, Crystal structures, Curran, Electron transfer, Equiv, Fensterbank, Flash chromatography, Geib, Gmbh, Halide, Insertion, Insertion product, Insertion products, Kgaa, Ldbb, Makhlouf brahmi, Malacria, Naphthalene, Naphthalenide, Sodium naphthalenide, Solovyev, Triplet, Verlag, Verlag gmbh, Weinheim, Weinheim angew.
- Teeft :
- Aliphatic, Aliphatic products, Alkyl, Alkyl halides, Angew, Angewandte, Anion, Boriranes, Boryl, Boryl dichlorides, Borylene, Braunschweig, Chem, Cleaner crude product, Crystal structures, Curran, Electron transfer, Equiv, Fensterbank, Flash chromatography, Geib, Gmbh, Halide, Insertion, Insertion product, Insertion products, Kgaa, Ldbb, Makhlouf brahmi, Malacria, Naphthalene, Naphthalenide, Sodium naphthalenide, Solovyev, Triplet, Verlag, Verlag gmbh, Weinheim, Weinheim angew.
Abstract
Still elusive: The reduction of dimethylimidazol‐2‐ylidene dichloroborane by sodium naphthalenide has been suggested to provide a borylene that cycloadds to naphthalene to make a borirane. Evidence has been provided that this borirane instead arises from coupling of a boryl radical and sodium naphthalenide. In contrast, reduction of 1,3‐bis(2,6‐diisopropylphenyl)imidazol‐2‐ylidene dichloroborane and the related dimesityl derivative provide novel CH insertion products that may have arisen from a borylene.
Url:
DOI: 10.1002/anie.201107238
Affiliations:
Links toward previous steps (curation, corpus...)
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- to stream Istex, to step Curation: 001747
- to stream Istex, to step Checkpoint: 001268
- to stream Main, to step Merge: 007D99
- to stream Main, to step Curation: 007922
Le document en format XML
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<front><div type="abstract">Still elusive: The reduction of dimethylimidazol‐2‐ylidene dichloroborane by sodium naphthalenide has been suggested to provide a borylene that cycloadds to naphthalene to make a borirane. Evidence has been provided that this borirane instead arises from coupling of a boryl radical and sodium naphthalenide. In contrast, reduction of 1,3‐bis(2,6‐diisopropylphenyl)imidazol‐2‐ylidene dichloroborane and the related dimesityl derivative provide novel CH insertion products that may have arisen from a borylene.</div>
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